Minerals By Class Minerals can be organized, mainly
according to their chemistry, into the
following classes
>> |
Elements Class: The Metals and Their Alloys and the Nonmetals. |
>> |
Sulfides Class: The Sulfides, the Selenides, the Tellurides, the Arsenides, the Antimonides, the Bismuthinides and the Sulfosalts. |
>> |
Halides Class: The Fluorides, the Chlorides and the Iodides. |
>> |
Oxides Class: The Oxides and the Hydroxides |
>> |
Carbonates Class: The Carbonates, the Nitrates and the Borates. |
>> |
Sulfates Class: The Sulfates,
the Sulfites, the Chromates, the Molybdates, the Selenates, the Selenites, the Tellurates, the
Tellurites and the Tungstates (or the Wolframates). |
>> |
Phosphates Class: The Phosphates, the Arsenates, the Vanadates and the Antimonates. |
>> |
Silicates Class: The Silicates (the largest class). |
>> |
The Organics Class: The "Minerals" composed of organic chemicals! |
>> |
The Mineraloids: The "Minerals" that lack crystal structure! |
The Native Elements ClassThe elements which include over one
hundred known minerals are a diverse
class when taken as a whole. Most of
this diversity, however, is due to the
diversity of the Non-metals Subclass.
The Metals Subclass and related metal
alloys contains metals whose properties
are rather similar due to the common way
in which they crystallize and bond. The
greatest difference in the metals is
color. The non-metals, however, are
extremely diverse. For instance, the
hardest mineral known to man is from
this subclass, as well as one of the
softest. The non-metals include some
elements known as semi-metals who share
some properties with metals but differ
in other characteristics.
Metal alloys are minerals that are
composed of combinations of different
metals in one mineral. All native metals
are impure usually by several percentage
points, but these are not distinguished
as distinct minerals unless they meet
certain mineralogical criteria.
Generally they must be consistent in
their composition and have their
respective elements occupy specific
sites in their crystal lattice in order
to be named as new minerals.
Alloys that are composed of semi-metals
with metals are classified as sulfides
but are sometimes listed as elements.
They usually share similarities to other
sulfides in their physical properties.
These minerals are in the Selenides, the
Tellurides, the Antimonides and the
Arsenides Subclasses of the Sulfide
Class. The main difference between
elemental alloys and these semi-metal
alloys is the presence of covalent
bonding in these minerals as opposed to
the strictly metallic bonding in pure
metals and their metal alloys.
The most difficult to classify are the
metal/non-metal mineral combinations.
These minerals, which combine metals
such as iron with the very non-metallic
elements of carbon, nitrogen,
phosphorous and silicon are quite unique
and quite rare. They are not too
different from sulfides which typically
combine metals with sulfur. But the
sulfides class is by convention limited
to sulfur and semi-metal combinations as
discussed above.
It might surprise people to find out
that the Elements Class contains
minerals that are composed of more than
one element. Elements, by the chemical
definition are composed of all the same
atoms; whereas substances composed of
two or more elements are compounds. The
inconsistency is explained by allowing
only those minerals whose bonding is
similar to the more traditional
elements. Metal alloys bond with
metallic bonds and the carbon-carbon
bond of diamond is similar to the
carbon-silicon bond in moissanite. This
type of covalent bonding is called
elemental bonds. All in all the Elements
Class is a rather complicated and interesting class of minerals.
Subclass: Native Metals: |
» | Cadmium Cd |
| Chromium Cr |
» |
The Gold Group:
| * Aluminum Al
* Copper Cu * Gold Au
* Lead Pb
* MercuryHg
* Silver Ag |
|
» | Indium In |
» | Iron Fe |
» | Nickel Ni |
» | The Platinum Group
|
* Iridium (Ir, Os, Ru)
* PalladiumPd
* PlatinumPt
* Rhodium (Rh, Pt) |
|
» | TelluriumTe |
» | Tin Sn |
» | Titanium Ti |
» | Zinc Zn |
Metallic Alloys: |
» | Anyuiite Au(Pb, Sb)2 |
» | AuricuprideCu3Au |
» | BelendorffiteCu7Hg6 |
» | Brass Cu3Zn2 |
» | Cabriite Pd2SnCu |
» | Chengdeite Ir3Fe |
» |
Cupalite (Cu, Zn)Al |
» | DanbaiteCuZn2 |
» | Eugenite Ag9Hg2 |
» | Hunchunite (Au, Ag)2Pb |
» | The Iron-nickel Group
| * IronFe
* Iron-nickel (Fe, Ni)
* Kamacite alpha - (Fe, Ni)
* Nickel Ni
* Taenite beta - (Fe, Ni)
* Tetrataenite FeNi
* WairauiteCoFe
|
|
» | Isoferroplatinum (Pt, Pd)3(Fe, Cu) |
» | Kolymite Cu7Hg6 |
» |
Leadamalgam HgPb2 |
» | LuanheiteAg3Hg |
» | Maldonite Au2Bi |
» | Moschellandsbergite Ag2Hg3 |
» |
Osmium (Os, Ir) |
» | Paraschachnerite Ag3Hg2 |
» |
Plumbopalladinite Pd3Pb2 |
» | SchachneriteAg1.1Hg0.9 |
» | Stannopalladinite (Pd, Cu)3Sn2 |
» | Tetraauricupride AuCu |
» | Tetraferroplatinum PtFe |
» | Weishanite (Au, Ag)3Hg2 |
» | Yuanjiangite AuSn |
» |
Zhanghengite (Cu, Zn, Fe, Al, Cr) |
Subclass: Native Non-metals and Semi-metals: |
» | Arsenic Group As:
|
* Antimony Sb
* Arsenic As
* Bismuth Bi
* Stibarsen SbAs
* Stistaite SnSb
|
|
» | Arsenolamprite As Carbon Group
|
* Chaoite C
* Diamond C
* Graphite C
* Lonsdaleite C
* Moissanite SiC |
|
» | Nierite Si3N4 |
» | ParadocrasiteSb2(Sb, As)2 |
» | Rosickyite S |
» | Selenium Se |
» | Silicon Si |
» | Sinoite Si2N2O |
» | Sulfur S |
» | Tellurium Te |
Minerals with metallic and non-metallic elements: |
» | Barringerite (Fe, Ni)2P |
» | Carlsbergite CrN |
» | Cohenite Fe3C |
» | Haxonite (Fe, Ni)23C6 |
» | Niggliite PtSn |
» | Nierite Si3N4 |
» | Osbornite TiN |
» | Perryite (Fe, Ni)8(Si, P)3 |
» | Roaldite Fe4N |
» | Schreibersite (Fe, Ni)3P |
» | Siderazot Fe5N2 |
» | Suessite (Fe, Ni)3Si |
» | Tongbaite Cr3C2 |
The Sulfides Class
As well as the Selenides, the Tellurides,
the Antimonides, the Arsenides and the Sulfosalts.
The members of the Sulfide Class form
an economically important class of
minerals. Most major ores of important
metals such as copper, lead and silver
are sulfides. Strong generalities exist
in this class. The majority of sulfides
are metallic, opaque, generally sectile,
soft to average in hardness and they
have high densities, black or dark
colored streaks and an igneous origin.
But, there are a few vitreous and
transparent members such as realgar,
cinnabar and orpiment that tend to break
the mold, so to speak.
Minerals belonging to the selenide,
telluride, antimonide and arsenide
subclasses have very similar properties
to the more common sulfides and are thus
included here. The whole or partial
supplanting of sulfur by either
selenium, tellurium, antimony, arsenic
or bismuth is possible because these
elements have similar sizes, charges and
ionic strengths. Only minerals in the
sulfide class that have no appreciable
sulfur are included in these subclasses.
If there is enough sulfur in the mineral
to be named in the formula than it is
treated as a normal sulfide.
Except in the case of the Sulfosalts.
This is a large segment of the sulfide
class whose difference from the other
sulfides lies in the position of the
semi-metal ions. In most ordinary
sulfides that contain a semi-metal such
as antimony, arsenic or bismuth, they
substitute in the sulfur positions, but
in sulfosalts they substitute for the
metal ions and bond with the sulfurs.
The term sulfosalts came from a theory
that these minerals were the salts of
acids in which the oxygens are replaced
by sulfurs. Such as Na2SO4 is the salt
of H2SO4 or sulfuric acid; then enargite,
Cu3AsS4. would be the salt of the
hypothetical acid H6AsS4. This theory is
not considered credible now but the name
"sulfosalt" still persists.
These are some of the members of the Sulfide Class:
The Standard Sulfides
» | Acanthite/Argentite (Silver Sulfide) |
» | Aguilarite (Silver Selenium Sulfide) |
» | Alabandite (Manganese Sulfide) |
» | Argentopentlandite (Silver Iron Nickel Sulfide) |
» | Argentopyrite (Silver Iron Sulfide) |
» | Argyrodite (Silver Germanium Sulfide) |
» | Arsenopyrite (Iron Arsenic Sulfide) |
» | Bismuthinite (Bismuth Sulfide) |
» | Bornite (Copper Iron Sulfide) |
» | Sulfide) |
» | Chalcocite (Copper Sulfide) |
» | Chalcopyrite (Copper Iron Sulfide) |
» | Cinnabar (Mercury Sulfide) |
» | Cobaltite (Cobalt Arsenic Sulfide) |
» | Covellite (Copper Sulfide) |
» | Cubanite (Copper Iron Sulfide) |
» | Digenite (Copper Sulfide) |
» | Famatinite (Copper Antimony Sulfide) |
» | Galena (Lead Sulfide) |
» | Germanite (Copper Germanium Gallium Iron Zinc Arsenic Sulfide) |
» | Gersdorffite (Nickel Arsenic Sulfide) |
» | Glaucodot (Copper Iron Arsenic Sulfide) |
» | Greenockite (Cadmium Sulfide) |
» | Hauchecornite (Nickel Bismuth Antimony Sulfide) |
» | Hauerite (Manganese Sulfide) |
» | Jalpaite (Silver Copper Sulfide) |
» | Kermesite (Antimony Oxysulfide) |
» | Laurite (Ruthenium Sulfide) |
» | Lautite (Copper Arsenic Sulfide) |
» | Linnaeite (Cobalt Sulfide) |
» | Marcasite (Iron Sulfide) |
» | Metacinnabar (Mercury Sulfide) |
» | Millerite (Nickel Sulfide) |
» | Molybdenite (Molybdenum Sulfide) |
» | Orpiment (Arsenic Sulfide) |
» | Patronite (Vanadium Sulfide) |
» | Pentlandite (Iron Nickel Sulfide) |
» | Polydymite (Nickel Sulfide) |
» | Pyrite (Iron Sulfide) |
» | Pyrrhotite (Iron Sulfide) |
» | Realgar (Arsenic Sulfide) |
» | Rheniite (Rhenium Sulfide) |
» | Schollhornite (Hydrated Sodium Chromium Sulfide) |
» | Siegenite (Cobalt Nickel Sulfide) |
» | Sphalerite (Zinc Iron Sulfide) |
» | Stannite (Copper Iron Tin Sulfide) |
» | Sternbergite (Silver Iron Sulfide) |
» | Stibnite (Antimony Sulfide) |
» | Stromeyerite (Silver Copper Sulfide) |
» | Teallite (Lead Tin Sulfide) |
» | Tetradymite (Bismuth Tellurium Sulfide) |
» | Tungstenite (Tungsten Sulfide) |
» | Ullmannite (Nickel Antimony Sulfide) |
» | Wurtzite (Zinc Iron Sulfide) |
|
» | Aikinite (Lead Copper Bismuth Sulfide) |
» | Andorite (Silver Lead Antimony Sulfide) |
» | Baumhauerite (Lead Arsenic Sulfide) |
» | Berthierite (Iron Antimony Sulfide) |
» | Boulangerite (Lead Antimony Sulfide) |
» | Bournonite (Lead Copper Antimony Sulfide) |
» | Chalcostibite (Copper Antimony Sulfide) |
» | Cylindrite (Iron Lead Tin Antimony Sulfide) |
» | Dufrenoysite (Lead Arsenic Sulfide) |
» | Emplectite (Copper Bismuth Sulfide) |
» | Enargite (Copper Arsenic Sulfide) |
» | Franckeite (Lead Tin Iron Antimony Sulfide) |
» | Freieslebenite (Silver Lead Antimony Sulfide) |
» | Geocronite (Lead Antimony Arsenic Sulfide) |
» | Gratonite (Lead Arsenic Sulfide) |
» | Hutchinsonite (Thallium Lead Arsenic Sulfide) |
» | Jamesonite (Lead Iron Antimony Sulfide) |
» | Jordanite (Lead Thallium Arsenic Antimony Sulfide) |
» | Matildite (Silver Bismuth Sulfide) |
» | Meneghinite (Copper Lead Antimony Sulfide) |
» | Miargyrite (Silver Antimony Sulfide) |
» | Owyheeite (Silver Lead Antimony Sulfide) |
» | Polybasite (Silver Copper Antimony Sulfide) |
» | Proustite (Silver Arsenic Sulfide) |
» | Pyrargyrite (Silver Antimony Sulfide) |
» | Sartorite (Lead Arsenic Sulfide) |
» | Schapbachite (Silver Bismuth Sulfide) |
» | Semseyite (Lead Antimony Sulfide) |
» | Smithite (Silver Arsenic Sulfide) |
» | Stephanite (Silver Antimony Sulfide) |
» | Tennantite (Copper Arsenic Sulfide) |
» | Tetrahedrite (Copper Iron Antimony Sulfide) |
» | Wittichenite (Copper Bismuth Sulfide) |
» | Wittite (Lead Bismuth Selenide Sulfide) |
» | Xanthoconite (Silver Arsenic Sulfide) |
» | Zinkenite (Lead Antimony Sulfide) |
|
» | Berzelianite (Copper Selenide) |
» | Clausthalite (Lead Selenide) |
» | Eucairite (Silver Copper Selenide) |
» | Klockmannite (Copper Selenide) |
» | Tiemannite (Mercury Selenide) |
» | Umangite (Copper Selenide) |
|
» | Altaite (Lead Telluride) |
» | Calaverite (Gold Telluride) |
» | Coloradoite (Mercury Telluride) |
» | Empressite (Silver Telluride) |
» | Hessite (Silver Telluride) |
» | Kostovite (Copper Gold Telluride) |
» | Krennerite (Silver Gold Telluride) |
» | Melonite (Nickel Telluride) |
» | Iron Telluride Sulfide) |
» | Petzite (Silver Gold Telluride) |
» | Rickardite (Copper Telluride) |
» | Sylvanite (Silver Gold Telluride) |
|
» | Aurostibite (Gold Antimonide) |
» | Breithauptite (Nickel Antimonide) |
» | Dyscrasite (Silver Antimonide) |
Subclass: Arsenides |
» | Domeykite (Copper Arsenide) |
» | Lollingite (Iron Arsenide) |
» | Maucherite (Nickel Arsenide) |
» | Nickeline (Nickel Arsenide) |
» | Nickel-skutterudite (chloanthite) (Nickel Arsenide) |
» | Rammelsbergite (Nickel Arsenide) |
» | Safflorite (Cobalt Iron Arsenide) |
» | Skutterudite (Cobalt Arsenide) |
» | Smaltite (Cobalt Nickel Arsenide) |
» | Sperrylite (Platinum Arsenide) |
These minerals are sometimes thought of as alloys of metals with semi-metals and placed in the Elements Class.
|
The Halides Class
The halides are a group of minerals
whose principle anions are halogens.
Halogens are a special group of elements
that usually have a charge of negative
one when chemically combined. The
halogens that are found commonly in
nature include Fluorine, Chlorine,
Iodine and Bromine. Halides tend to have
rather simply ordered structures and
therefore a high degree of symmetry. The
most famous halide mineral, halite (NaCl)
or rock salt has the highest symmetry
4/m bar 3 2/m. The colorful mineral
fluorite (CaF) also has 4/m bar 3 2/m
symmetry and its cubic crystals are very
popular mineral specimens. There are
only a few common halide minerals. The
typical halide mineral is soft, can be
transparent, is generally not very
dense, has good cleavage, and often has
bright colors.
MINERALS OF THE HALIDE CLASS:
» | Atacamite (Copper Chloride Hydroxide) |
» | Avogadrite (Potassium Cesium Boron Fluoride) |
» | Bararite (Ammonium Silicon Fluoride) |
» | Bischofite (Hydrated Magnesium Chloride) |
» | Bismoclite (Bismuth Chloride Oxide) |
» | Boleite (Hydrated Lead Copper Silver Chloride Hydroxide) |
» | Calomel (Mercury Chloride) |
» | Camermanite (Potassium SiliconFluoride) |
» | Carnallite (Hydrated Potasium Magnesium Chloride) |
» | Chiolite (Sodium Aluminum Fluoride) |
» | Chlorargyrite (Silver Chloride) |
» | Chlorocalcite (Potassium Calcium Chloride) |
» | Chloromanganokalite (Potassium Manganese Chloride) |
» | Chloroxiphite (Lead Copper Chloride Oxide Hydroxide) |
» | Cotunnite (Lead chloride) |
» | Cryolite (Sodium Aluminum Fluoride) |
» | Cryolithionite (Lithium Sodium Aluminum Fluoride) |
» | Cryptohalite (Ammonium Silicon Fluoride) |
» | Cumengeite (Hydrated Lead Copper Chloride Hydroxide) |
» | Diaboleite (Lead Copper Chloride Hydroxide) |
» | Douglasite (Hydrated Potassium Iron Chloride) |
» | Embolite (Silver Chloride Bromide) |
» | Erythrosiderite (Hydrated Potassium Iron Chloride) |
» | Ferruccite (Sodium Boron Fluoride) |
» | Fiedlerite (Lead Chloride Hydroxide) |
» | Fluocerite (Cerium Lanthanum Fluoride) |
» | Fluorite (Calcium Fluoride) |
» | Halite (Sodium Chloride) |
» | Hieratite (Potassium Silicon Fluoride) |
» | Jarlite (Sodium Strontium Aluminum Fluoride) |
» | Kempite (Manganese Chloride Hydroxide) |
» | Laurionite (Lead Chloride Hydroxide) |
» | Lawrencite (Iron Chloride) |
» | Lorettoite (Lead Chloride Oxide) |
» | Malladrite (Sodium Silicon Fluoride) |
» | Marshite (Copper Iodide) |
» | Matlockite (Lead Fluoride Chloride) |
» | Mendipite (Lead Chloride Oxide) |
» | Miersite (silver copper Iodide) |
» | Nantokite (Copper Chloride) |
» | Pachnolite (Hydrated Calcium Sodium Aluminum Fluoride) |
» | Paralaurionite (Lead Chloride Hydroxide) |
» | Penfieldite (Lead Chloride Hydroxide) |
» | Prosopite (Calcium Aluminum Fluoride Hydroxide) |
» | Pseudoboleite (Hydrated Lead Copper Chloride Hydroxide) |
» | Ralstonite (Hydrated Sodium Magnesium Aluminum Fluoride Hydroxide) |
» | Rinneite (Potassium Sodium Iron Chloride) |
» | Sal Ammoniac (Ammonium Chloride) |
» | Scacchite (Manganese Chloride) |
» | Sellaite (Magnesium Fluoride) |
» | Sylvite (Potassium Chloride) |
» | Tachhydrite (Hydrated Calcium Magnesium Chloride) |
» | Thomsenolite (Hydrated CalciumSodium Aluminum Fluoride) |
» | Villiaumite (Sodium Fluoride) |
The Oxides Class
Including both Oxides and Hydroxides
The oxide class of minerals is a rather
diverse class. It includes minerals that
are quite hard (corundum) and some that
are quite soft such as psilomelane. It
has metallic minerals such as hematite
and gemstones such as corundum,
chrysoberyl and spinel. Many oxides are
black but others can be very colorful.
The large diversity of oxides can be
partially attributed to the extreme
abundance of oxygen in the Earth's
crust. Oxygen comprises over 45% of the
Earth's crust by weight. Most of this is
locked up in more complex minerals based
on chemical complex anions such as CO3,
BO3, SO4, NO3, SiO4, PO4 and others. But
great opportunities exist for single
oxygen ions to combine with various
elements in many different ways. In a
strict sense, minerals that belong to
the more complex mineral classes such as
the Silicates are really oxides. But
this would be cumbersome for
mineralogists to be able to deal with
only the four different classes of the
elements class, the halides class, the
sulfides class and finally the extremely
large oxides class with all of its many
subclasses and over 90% of all known
minerals. By convention therefore, the
oxides are limited to non complex
minerals containing oxygen or hydroxide.
Oxides also contain mostly ionic bonds
and this helps distinguish members from
the more complex mineral classes whose
bonds are typically more covalent in
nature. Quartz, SiO2, would be
considered an oxide, and still is in
some mineral guides and texts, except
for its covalent silicon oxygen bonds
and its structural similarity to the
other TectoSilicates.
Hydrogen in the positive one (+1) state
is really only a single proton and is so
small that when it combines with oxygen
it disappears into the oxygen and the
resulting OH group is almost the same
size as a single oxygen ion with a
negative two (-2) charge. Hence the OH
group can fit into many crystal sites
that oxygen would otherwise occupy, but
with a charge of only negative one (-1).
The crystal would then need to be balanced by additional negative charges or fewer positive charges.
Oxides: |
» | Aeschynite (Rare Earth Yttrium Titanium Niobium Oxide Hydroxide) |
» | Anatase (Titanium Oxide) |
» | Bindheimite (Lead Antimony Oxide Hydroxide) |
» | Bixbyite (Manganese Iron Oxide) |
» | Brookite (Titanium Oxide) |
» | Chrysoberyl (Beryllium Aluminum Oxide) |
» | Columbite (Iron Manganese Niobium Tantalum Oxide) |
» | Corundum (Aluminum Oxide) |
» | Cuprite (Copper Oxide) |
» | Euxenite (Rare Earth Yttrium Niobium Tantalum Titanium Oxide) |
» | Fergusonite (Rare Earth Iron Titanium Oxide) |
» | Hausmannite (Manganese Oxide) |
» | Hematite (Iron Oxide) |
» | Ice (Hydrogen Oxide) |
» | Ilmenite (Iron Titanium Oxide) |
» | Perovskite (Calcium Titanium Oxide) |
» | Periclase (Magnesium Oxide) |
» | Polycrase (Rare Earth Yttrium Titanium Niobium Tantalum Oxide) |
» | Pseudobrookite (Iron Titanium Oxide) |
» | The Pyrochlore Group
| (Rare Earths Calcium Sodium Uranium Titanium Niobium Tantalum Oxide Hydroxide)
* Microlite (Calcium Sodium Tantalum Oxide Hydroxide Fluoride)
* Pyrochlore (Sodium Calcium Niobium Oxide Hydroxide Fluoride) |
|
» | Ramsdellite (Manganese Oxide) |
» | Romanechite (Hydrated Barium Manganese Oxide) |
» | The Rutile Group:
| * Cassiterite (Tin Oxide)
* Plattnerite (Lead Oxide)
* Pyrolusite (Manganese Oxide)
* Rutile (Titanium Oxide)
* Stishovite (Silicon Oxide) |
|
» | Samarskite-(Y) (Rare Earth Yttrium Iron Titanium Oxide) |
» | Senarmontite (Antimony Oxide) |
» |
The Spinel Group:
| * chromate (Iron Chromium Oxide)
* Franklinite (Zinc Manganese Iron Oxide)
* Gahnite (Zinc Aluminum Oxide)
* Magnesiochromate (Magnesium Chromium Oxide)
* Magnetite (Iron Oxide)
* Spinel (Magnesium Aluminum Oxide)
|
|
» | Taaffeite (Beryllium Magnesium Aluminum Oxide) |
» | Tantalite (Iron Manganese Tantalum Niobium Oxide) |
» | Tapiolite (Iron Manganese Tantalum Niobium Oxide) |
» | Uraninite (Uranium Oxide) |
» | Valentinite (Antimony Oxide) |
» | Zincite(Zinc Manganese Oxide) |
Subclass: Hydroxides |
» | Brucite (Magnesium Hydroxide) |
» | Gibbsite (Aluminum Hydroxide) |
» | Goethite (Iron Oxide Hydroxide) |
» | Limonite (Hydrated Iron Oxide Hydroxide) |
» | Manganite (Manganese Oxide Hydroxide) |
» | Psilomelane(Barium Manganese Oxide Hydroxide) |
» | Romeite (Calcium Sodium Iron Manganese Antimony Titanium Oxide Hydroxide) |
» | Stetefeldtite (Silver Antimony Oxide Hydroxide) |
» | Stibiconite (Antimony Oxide Hydroxide) |
The Carbonates Class
Including the Carbonates, the Uranyl Carbonates , the Rare Earth Carbonates, the Nitrates, the Iodates and the Borates.
The carbonates and related nitrates and
borates are common constituents of the
earth's near-surface crust. This is a
structurally-related as well as
chemically-related group The basic
anionic (negatively charged) unit of
this class consists of a triangle where
at the center resides either a carbon,
nitrogen or boron atom. At every corner
of the triangle sits an oxygen atom. The
threefold symmetry of the triangle
explains the trigonal symmetry that many
members of this class possess. As long
as the triangles of the anionic group
fall in a plane parallel with the plane
of the triangle and all other bonds in
the structure, when viewed perpendicular
to this plane, are multiples of three,
and are evenly separated from each
other, the mineral will have a trigonal
symmetry.
As complicated as this seems it is in
fact the simplest condition of the
carbonates. Simplicity often expresses
the highest symmetry. As a sphere is
more symmetrical than a football; a
simple carbonate is more symmetrical
than a more complex carbonate and in
fact has the highest symmetry of this
class, bar 3 2/m.
Although somewhat varied, this class'
properties can be generalized more so
than the other classes. Typical
carbonates are transparent, lightly
colored with a white streak, average to
above average in density, soft with good
to perfect cleavage, soluble to at least
some degree in acidic solutions, and
tend to originate in sedimentary and
oxidizing environments with the
exception of carbonatite igneous
intrusions. Most of these common
characteristics are due to the common
chemistry the group shares and members
that diverge from the norm do so because
of the effects of metal cations such as
lead, copper, manganese and iron.
The Borate minerals as a whole are more
complex in their structures than typical
carbonates and could be considered their
own class for that reason. For more
discussion and a rather extensive list
of borate minerals see the Borate
Minerals page.
The Carbonates |
» | Alstonite (Barium Calcium Carbonate) |
» | Alumohydrocalcite (Hydrated Calcium Aluminum Carbonate Hydroxide) |
» |
| *Aragonite (Calcium Carbonate)
* Cerussite (Lead Carbonate)
* Strontianite (Strontium Carbonate)
* Witherite (Barium Carbonate) |
|
» | Artinite (Hydrated Magnesium Carbonate Hydroxide) |
» | Aurichalcite (Zinc Copper Carbonate Hydroxide) |
» | Azurite (Copper Carbonate Hydroxide) |
» | Barbertonite (Hydrated Magnesium Chromium Carbonate Hydroxide) |
» | Barentsite (Sodium Aluminum Carbonate Hydroxide Fluoride) |
» | Barringtonite(Hydrated Magnesium Carbonate) |
» | Barytocalcite (Barium Calcium Carbonate) |
» | Baylissite (Hydrated Potassium Magnesium Carbonate) |
» | Beyerite (Calcium Lead Bismuth Carbonate Oxide) |
» | Bismutite (Bismuth Carbonate Oxide) |
» | Brenkite (Calcium Carbonate Fluoride) |
» | Brugnatellite (Hydrated Magnesium Iron Carbonate Hydroxide) |
» | Butschliite (Potassium Calcium Carbonate) |
» | The Calcite Group:
|
* Calcite (Calcium Carbonate)
* Gaspeite (Nickel Magnesium Iron Carbonate)
* Magnesite (Magnesium Carbonate)
* Otavite (Cadmium Carbonate)
* Rhodochrosite (Manganese Carbonate)
* Siderite (Iron Carbonate)
* Smithsonite (Zinc Carbonate)
* Sphaerocobaltite (Cobalt Carbonate)
|
|
» | Caresite (Hydrated Iron Aluminum Carbonate Hydroxide) |
» | Chalconatronite (Hydrated Sodium Copper Carbonate) |
» | Charmarite (Hydrated Manganese Aluminum Carbonate Hydroxide) |
» | Dawsonite (Sodium Aluminum Carbonate Hydroxide) |
» | The Dolomite Group:
| * Ankerite (Calcium Iron Carbonate)
* Benstonite (Barium Strontium Calcium Manganese Magnesium Carbonate)
* Dolomite (Calcium Magnesium Carbonate)
* Huntite (Calcium Magnesium Carbonate)
* Kutnohorite (Calcium Manganese Magnesium Iron Carbonate)
* Minrecordite (Calcium Zinc Carbonate)
* Norsethite (Barium Magnesium Carbonate) |
|
» | Dresserite (Hydrated Barium Aluminum Carbonate Hydroxide) |
» | Dundasite(Hydrated Lead Aluminum Carbonate Hydroxide) |
» | Eitelite (Sodium Magnesium Carbonate) |
» | Fairchildite (Potassium Calcium Carbonate) |
» | Gaylussite (Hydrated Sodium Calcium Carbonate) |
» | Georgeite (Hydrated Copper Carbonate Hydroxide) |
» | Hellyerite (Hydrated Nickel Carbonate) |
» | Hydrocerussite (Lead Carbonate Hydroxide) |
» | Hydrodresserite (Hydrated Barium Aluminum Carbonate Hydroxide) |
» | Hydrotalcite (Hydrated Magnesium Aluminum Carbonate Hydroxide) |
» | Hydrozincite (Zinc Carbonate Hydroxide) |
» | Ikaite(Hydrated Calcium Carbonate) |
» | Indigirite (Hydrated Magnesium Aluminum Carbonate Hydroxide) |
» | Kalicinite (Potassium Bicarbonate) |
» | Kambaldaite (Hydrated Sodium Nickel Carbonate Hydroxide) |
» | Kettnerite (Calcium Bismuth Carbonate Oxide) |
» | Lansfordite (Hydrated Magnesium Carbonate) |
» | Leadhillite (Lead Sulfate Carbonate Hydroxide) |
» | Liebigite (Hydrated Calcium Uranyl Carbonate) |
» | Loseyite(Manganese Zinc Carbonate Hydroxide) |
» | Macphersonite (Lead Sulfate Carbonate Hydroxide) |
» | Malachite (Copper Carbonate Hydroxide) |
» | Manasseite (Hydrated Magnesium Aluminum Carbonate Hydroxide) |
» | Monohydrocalcite (Hydrated Calcium Carbonate) |
» | Nahcolite (Sodium Bicarbonate) |
» | Natrite (Sodium Carbonate) |
» | Natrofairchildite (Sodium Calcium Carbonate) |
» | Natron (Hydrated Sodium Carbonate) |
» | Nesquehonite(Hydrated Magnesium Bicarbonate Hydroxide) |
» | Northupite (Sodium Magnesium Carbonate Chloride) |
» | Nyerereite (Sodium Calcium Carbonate) |
» | Olekminskite (Strontium Calcium Barium Carbonate) |
» | Paralstonite (Barium Calcium Carbonate) |
» | Para-alumohydrocalcite (Hydrated Calcium Aluminum Carbonate Hydroxide) |
» | Phosgenite (Lead Carbonate Cloride) |
» | Pirssonite (Hydrated Sodium Calcium Carbonate) |
» | Plumbonacrite (Lead Carbonate Oxide Hydroxide) |
» | Pokrovskite (Hydrated Magnesium Carbonate Hydroxide) |
» | Pyroaurite (Hydrated Magnesium Iron Carbonate Hydroxide) |
» | Quintinite (Hydrated Magnesium Aluminum Carbonate Hydroxide) |
» | The Rosasite Group:
|
* Glaukospherite (Copper Nickel Carbonate Hydroxide)
* Kolwezite (Copper Cobalt Carbonate Hydroxide)
* Mcguinnessite (Magnesium Copper Carbonate Hydroxide)
* Nullaginite (Nickel Carbonate Hydroxide)
* Rosasite (Copper Zinc Carbonate Hydroxide)
* Zincrosasite (Zinc Copper Carbonate Hydroxide) |
|
» | Rouvilleite(Sodium Calcium Manganese Carbonate Fluoride Hydroxide) |
» | Sabinaite (Sodium Zirconium Titanium Carbonate Oxide) |
» | Sclarite (Zinc Magnesium Manganese Carbonate Hydroxide) |
» | Sergeevite (Hydrated Calcium Magnesium Carbonate Bicarbonate Hydroxide) |
» | Shannonite (Lead Carbonate Oxide) |
» | Sheldrickite (Hydrated Sodium Calcium Carbonate Fluoride) |
» | Shortite (Sodium Calcium Carbonate) |
» | Sjogrenite (Hydrated Magnesium Iron Carbonate Hydroxide) |
» | Stichtite (Hydrated Magnesium Chromium Carbonate Hydroxide) |
» | Strontiodresserite (Hydrated Strontium Calcium Aluminum Carbonate Hydroxide) |
» | Susannite (Lead Sulfate Carbonate Hydroxide) |
» | Szymanskiite (Hydrated Mercury Nickel Magnesium Carbonate Oxide Hydroxide) |
» | Teschemacherite (Ammonia Bicarbonate) |
» | Thermonatrite (Hydrated Sodium Carbonate) |
» | Trona (Hydrated Sodium Carbonate Bicarbonate) |
» | Tunisite (Sodium Calcium Aluminum Carbonate Hydroxide Chloride) |
» | Tychite (Sodium Magnesium
Carbonate Sulfate) |
» | Vaterite (Calcium Carbonate) |
» | Wegscheiderite (Sodium Carbonate
Bicarbonate) |
» | Weloganite (Hydrated Sodium
Strontium Calcium Zirconium
Carbonate) |
» | Zaratite (Hydrated Nickel
Carbonate Hydroxide) |
» | Zemkorite (Sodium Potassium
Calcium Carbonate) |
The Uranyl Carbonates |
» | Andersonite(Hydrated Sodium Calcium Uranyl Carbonate) |
» | Astrocyanite-(Ce) (Hydrated
Copper Cerium Neodymium
Lanthanum Praseodymium Samarium
Calcium Yttrium Uranyl Carbonate
Hydroxide) |
» | Bayleyite (Hydrated Magnesium Uranyl Carbonate) |
» | Bijvoetite-(Y) (Hydrated Yttrium Dysprosium Uranyl Carbonate Hydroxide) |
» | Fontanite (Hydrated Calcium Uranyl Carbonate) |
» | Grimselite (Hydrated Potassium Sodium Uranyl Carbonate) |
» | Joliotite (Hydrated Uranyl Carbonate) |
» | Liebigite (Hydrated Calcium Uranyl Carbonate) |
» | Metazellerite (Hydrated Calcium Uranyl Carbonate) |
» | Rabbittite (Hydrated Calcium Magnesium Uranyl Carbonate Hydroxide) |
» | Roubaultite (Copper Uranyl Carbonate Oxide Hydroxide) |
» | Rutherfordine (Uranyl Carbonate) |
» | Schrokingerite (Hydrated Sodium Calcium Uranyl Sulfate Carbonate Fluoride) |
» | Shabaite (Hydrated Copper Cerium Neodymium Lanthanum Praseodymium Samarium Calcium Yttrium Uranyl Carbonate Hydroxide) |
» | Sharpite (Hydrated Calcium
Uranyl Carbonate Hydroxide) |
» | Swartzite (Hydrated Calcium
Magnesium Uranyl Carbonate) |
» | Voglite (Hydrated Calcium Copper
Uranyl Carbonate) |
» | Widenmannite(Lead Uranyl Carbonate) |
» | Zellerite (Hydrated Calcium
Uranyl Carbonate) |
» | Znucalite (Hydrated Calcium Zinc
Uranyl Carbonate Hydroxide) |
The Rare Earth Carbonates |
» | Ancylite-(Ce) (Hydrated Cerium
Lanthanum Strontium Calcium
Carbonate Hydroxide) |
» | Baiyuneboite-(Ce) (Sodium Barium
Cerium Carbonate Fluoride) |
» | Bastnasite (Cerium Lanthanum
Yttrium Carbonate Fluoride) |
» | Burbankite (Sodium Calcium
Strontium Barium Cerium
Carbonate) |
» | Calcioancylite (Hydrated Calcium
Strontium Cerium Neodymium
Carbonate Hydroxide) |
» | Calkinsite-(Ce) (Hydrated Cerium
Lanthanum Carbonate) |
» | Carbocernaite (Calcium Sodium
Strontium Cerium Barium
Carbonate) |
» | Cebaite (Barium Cerium Neodymium
Carbonate Fluoride) |
» | Cordylite-(Ce) (Barium Cerium
Lanthanum Carbonate Fluoride) |
» | Daqingshanite-(Ce) (Strontium
Calcium Barium Cerium Lanthanum
Phosphate Carbonate Hydroxide
Fluoride) |
» | Donnayite-(Y) (Hydrated Sodium
Strontium Calcium Yttrium
Carbonate) |
» | Ewaldite (Barium Calcium Yttrium
Sodium Potassium Carbonate) |
» | Gysinite-(Nd) (Hydrated
Neodymium Lead Carbonate
Hydroxide) |
» | Horvathite-(Y) (Sodium Yttrium
Carbonate Fluoride) |
» | Huanghoite-(Ce) (Barium Cerium
Carbonate Fluoride) |
» | Hydroxylbasnasite (Cerium
Lanthanum Neodymium Carbonate
Hydroxide Fluoride) |
» | Hydroxylcarbonate-(Nd) (Cerium
Lanthanum Neodymium Carbonate
Hydroxide) |
» | Khanneshite (Sodium Calcium
Barium Strontium Cerium
Carbonate) |
» | Kimuraite-(Y) (Hydrated Calcium
Yttrium Carbonate) |
» | Lanthanite (Hydrated Cerium
Lanthanum Neodymium Carbonate) |
» | lokkaite-(Y)
(Hydrated Calcium Yttrium
Carbonate) |
» | Mckelveyite-(Y) (Hydrated Barium
Sodium Calcium Uranium Yttrium
Carbonate) |
» | Parisite (Calcium Cerium
Lanthanum Neodymium Carbonate
Fluoride) |
» | Reederite-(Y) (Sodium Yttrium
Carbonate Sulfate Chloride) |
» | Remondite-(Ce) (Sodium Cerium
Lanthanum Calcium Strontium
Carbonate) |
» | Rontgenite-(Ce) (Calcium Cerium
Lanthanum Carbonate Fluoride) |
» | Sahamalite-(Ce) (Magnesium Iron
Cerium Lanthanum Neodymium
Carbonate) |
» | Schuilingite-(Nd) (Hydrated Lead
Copper Neodymium Gadolinium
Samarium Yttrium Carbonate
Hydroxide) |
» | Shomiokite (Hydrated Sodium
Yttrium Carbonate) |
» | Synchysite (Calcium Cerium
Lanthanum Neodymium Yttrium
Carbonate Fluoride) |
» | Tengerite-(Y) (Hydrated Calcium Yttrium Carbonate Hydroxide) |
» | Thorbastnasite (Hydrated Thorium Calcium Cerium Carbonate Fluoride) |
» | Tuliokite (Hydrated Barium Sodium Thorium Carbonate) |
» | Tundrite(Sodium Cerium Neodymium Lanthanum Titanium Niobium Silicate Carbonate Oxide Hydroxide) |
» | Zhonghuacerite-(Ce) (Barium Cerium Carbonate Fluoride) |
See also mineral lists of these
subclasses: the Borates, Nitrates and Iodates
The Sulfates Class
Included in this class are various
subclasses: the Sulfites, the Chromates,
the Molybdenates, the Selenates and
Selenites, theTellurates and Tellurites and the Tungstates.
The Sulfates are an important mineral
class and include some very
interestingand attractive specimens.
Although many minerals belong to this
class only barite, gypsum, and anhydrite
can be considered common. The basic
chemical unit is the (AO4) complex anion
with a charge of negative two (-2). The
sulfites, selenites and tellurites
(notice the spelling) have a basic unit
of (AO3)The A can be either sulfur (S),
chromium (Cr), tungsten (W),selenium
(Se), tellurium (Te) and/or molybdenium
(Mo). The principle anion group
nevershares oxygens with other principle
anion groups and this limits the
structural possibilities. The A atom at
the center of the AO4anion has a
positive six charge (+6) and the oxygens
have their obligatory negative two
charge (-2). The AO4 anions form
symmetricaltetrahedrons when A is either
sulfur or chromium and flattened
tetrahedronswhen A is either molybdenium,
selenium or tungsten. The flattened
tetrahedrons form a square outline and
help produce (in most of those minerals)
a tetragonal(four fold) symmetry, which
is an uncommon symmetry in minerals. The
typical Sulfate Class mineral is
vitreous, average to above average in
density,average in hardness and are
originally formed in veins, oxidation
zones,contact metamorphic zones and in
evaporite deposits. Some Sulfate Class
minerals are soluble and several are
fluorescent. All other properties are
variable.
Subclass: Sulfates |
» | Aluminite (Hydrated Aluminum
Sulfate Hydroxide) |
» | The Alunite Group: |
» | The Alunite Subgroup:
| * Alunite
(Potassium Aluminum Sulfate Hydroxide)
* Ammonioalunite (Ammonium
Aluminum Sulfate
Hydroxide)
* Huangite
(Calcium
Aluminum Sulfate Oxide
Hydroxide)
* Minamiite
(Sodium
Calcium Potassium
Aluminum Sulfate
Hydroxide)
* Natroalunite
(Sodium
Aluminum Sulfate
Hydroxide)
* Osarizawaite (Lead
Copper Aluminum Sulfate
Hydroxide)
* Walthierite
(Barium
Aluminum Sulfate Oxide
Hydroxide) | |
» | The Jarosite Subgroup:
|
* Ammoniojarosite (Ammonium
Iron Sulfate Hydroxide)
* Argentojarosite
(Silver Iron Sulfate
Hydroxide)
* Beaverite (Lead Copper
Iron Aluminum Sulfate
Hydroxide)
* Dorallcharite
(Thallium
Potassium Iron Sulfate
Hydroxide)
* Hydroniumjarosite
(Hydronium
Iron Sulfate Hydroxide)
* Jarosite (Potassium
Iron Sulfate Hydroxide)
* Natrojarosite (Sodium
Iron Sulfate Hydroxide)
* Plumbojarosite
(Lead
Iron Sulfate Hydroxide) |
|
» |
Amarantite (Hydrated Iron Sulfate
Hydroxide) |
» |
Ammonioalunite (Ammonium Aluminum
Sulfate Hydroxide) |
» |
Anhydrite (Calcium Sulfate) |
» |
Aphthitalite (Potassium Sodium
Sulfate) |
» |
Argentojarosite (Silver Iron
Sulfate Hydroxide) |
» | The
Barite Group:
|
* Anglesite
(Lead
Sulfate)
*
Barite
(Barium Sulfate)
* Celestite (Strontium
Sulfate)
* Hashemite
(Barium
Chromate Sulfate) |
|
» |
Beaverite(Copper
Iron Aluminum Sulfate Hydroxide) |
» | The Beudantite Group:
| *
Beudantite Lead Iron
Arsenate Sulfate
Hydroxide
* Corkite
(Lead Iron
Phosphate Sulfate
Hydroxide)
* Gallobeudantite (Lead
Gallium Arsenate Sulfate
Hydroxide)
* Hidalgoite
(Lead
Aluminum Arsenate
Sulfate Hydroxide)
* Hinsdalite
(Lead
Strontium Aluminum
Phosphate Sulfate
Hydroxide)
* Kemmlitzite
(Strontium
Cerium Aluminum Arsenate
Sulfate Hydroxide)
* Orpheite
(Lead
Aluminum Phosphate
Sulfate Hydroxide)
* Schlossmacherite
(Hydrated Hydrogen
Calcium Aluminum
Arsenate Sulfate
Hydroxide)
* Svanbergite
(Strontium
Aluminum Phosphate
Sulfate Hydroxide)
* Woodhouseite
(Calcium
Aluminum Arsenate
Sulfate Hydroxide) |
|
» |
Blodite (Hydrated Sodium
Magnesium Sulfate) |
» |
Botryogen (Hydrated Magnesium
Iron Sulfate Hydroxide) |
» |
Brochantite (Copper Sulfate
Hydroxide) |
» |
Burkeite (Sodium Carbonate
Sulfate) |
» |
Butlerite (Hydrated Iron Sulfate
Hydroxide) |
» |
Caledonite(Copper
Lead Carbonate Sulfate
Hydroxide) |
» | The Chalcanthite Group
| *
Chalcanthite
(Hydrated
Copper Sulfate)
* Jokokuite
(Hydrated
Manganese Sulfate)
* Pentahydrite (Hydrated
Magnesium Sulfate)
* Siderotil (Hydrated
Iron Sulfate) |
|
» |
Charlesite (Hydrated Calcium
Aluminum Silicon Hydroborate
Sulfate Hydroxide) |
» |
Chessexite (Hydrated Sodium
Calcium Magnesium Zinc Aluminum
Silicate Sulfate Hydroxide) |
» |
Connellite (Hydrated Copper
Sulfate Hydroxide Chloride) |
» |
Copiapite(Hydrated
Iron Magnesium Sulfate
Hydroxide) |
» |
Creedite (Hydrated Calcium
Aluminum Sulfate Fluroide
Hydroxide) |
» |
Cyanotrichite (Hydrated Copper
Aluminum Sulfate Hydroxide) |
» |
Despujolsite (Hydrated Calcium
Manganese Sulfate Hydroxide) |
» |
Devilline (Hydrated Calcium
Copper Sulfate Hydroxide) |
» |
Epsomite (Hydrated Magnesium
Sulfate) |
» |
Ettringite (Hydrated Calcium
Aluminum Sulfate Hydroxide) |
» |
Glauberite (Sodium Calcium
Sulfate) |
» |
Goslarite (Hydrated Zinc Sulfate) |
» |
Gypsum(Hydrated
Calcium Sulfate) |
» | The Halotrichite Group
| *
Apjohnite
(Hydrated
Manganese Aluminum
Sulfate)
* Bilinite (Hydrated Iron
Sulfate)
* Dietrichite
(Hydrated
Zinc Iron Manganese
Aluminum Sulfate)
* Halotrichite
(Hydrated
Iron Aluminum Sulfate)
* Pickeringite
(Hydrated
Magnesium Aluminum
Sulfate)
* Redingtonite (Hydrated
Iron Magnesium Nickel
Chromium Aluminum
Sulfate)
* Wupatkiite
(Hydrated
Cobalt Magnesium Nickel
Aluminum Sulfate) |
|
» |
Hanksite (Sodium Potassium
Carbonate Sulfate Chloride) |
» |
Hauckite (Magnesium Manganese
Zinc Iron Carbonate Sulfate
Hydroxide) |
» |
Hectorfloresite (Sodium Iolate
Sulfate) |
» |
Heidornite (Sodium Calcium Borate
Sulfate Chloride Hydroxide) |
» |
Hexahydrite (Hydrated Magnesium
Sulfate) |
» |
Humberstonite (Hydrated Potassium
Sodium Magnesium Nitrate
Sulfate) |
» |
Johannite (Hydrated Copper Uranyl
Sulfate Hydroxide) |
» |
Jouravskite (Hydrated Calcium
Manganese Carbonate Sulfate
Hydroxide) |
» | The Kieserite Group
| *
Dwornikite
(Hydrated
Nickel Iron Sulfate)
* Gunningite (Hydrated
Zinc Manganese Sulfate)
* Kieserite (Hydrated
Magnesium Sulfate)
* Poitevinite
(Hydrated
Copper Iron Zinc
Sulfate)
* Szmikite
(Hydrated
Manganese Sulfate)
* Szomolnokite
(Hydrated
Iron Sulfate) |
|
» |
Ktenasite (Hydrated
Copper Zinc Sulfate Hydroxide) |
» |
Lanarkite(Lead
Sulfate) |
» |
Langite (Hydrated Copper Sulfate
Hydroxide) |
» |
Linarite (Lead Copper Sulfate
hydroxide) |
» | The Melanterite Group
| * Bieberite
(Hydrated
Cobalt Sulfate)
* Boothite
(Hydrated
Copper Sulfate)
* Mallardite
(Hydrated
Manganese Sulfate)
* Melanterite
(Hydrated
Iron Sulfate)
* Zinc-melanterite (Hydrated
Zinc Copper Iron
Sulfate) |
|
» |
Mirabilite (Hydrated Sodium
Sulfate) |
» |
Mooreite (Hydrated Magnesium Zinc
Manganese Sulfate Hydroxide) |
» |
Morenosite (Hydrated Nickel
Sulfate) |
» |
Mountkeithite (Hydrated Magnesium
Nickel Iron Chromium Aluminum
Carbonate Sulfate Hydroxide) |
» |
Nakauriite (Hydrated Copper
Carbonate Sulfate Hydroxide) |
» |
Picromerite (Hydrated Potassium
Magnesium Sulfate) |
» |
Plumbojarosite (Lead Iron Sulfate
Hydroxide) |
» |
Polyhalite (Hydrated Potassium
Calcium Magnesium Sulfate) |
» |
Potassium alum (Hydrated
Potassium Aluminum Sulfate) |
» |
Rapidcreekite (Hydrated Calcium
Carbonate Sulfate) |
» |
Retgersite (Hydrated Nickel
Sulfate) |
» | The Rozenite Group
| *
Starkeyite
(Hydrated
Cobalt Manganese Nickel
Sulfate)
* Boyleite
(Hydrated
Zinc Magnesium Sulfate)
* Ilesite
(Hydrated
Manganese Zinc Iron
Sulfate)
* Rozenite (Hydrated
Iron Sulfate)
* Starkeyite
(Hydrated
Magnesium Sulfate) |
|
» |
Serpierite (Hydrated Calcium
Copper Zinc Sulfate Hydroxide) |
» |
Spangolite(Hydrated
Copper Aluminum Sulfate
Hydroxide Chloride) |
» |
Sturmanite(Hydrated
Calcium Iron Aluminum Manganese
Sulfate Tetrahydroxoborate
Hydroxide) |
» |
Tatarskite (Hydrated CAlcium
Magnesium Carbonate Sulfate
Chloride Hydroxide) |
» |
Thaumasite (Hydrated Calcium
Silicon Carbonate Sulfate
Hydroxide) |
» |
Thenardite (Sodium Sulfate) |
» |
Torreyite (Hydrated Magnesium
Manganese Zinc Sulfate
Hydroxide) |
» |
Ungemachite (Hydrated
Potassium Sodium Iron Nitrate
Sulfate) |
» |
Uranopilite(Hydrated
Uranyl Sulfate Hydroxide) |
» |
Vanthoffite (Sodium Magnesium
Sulfate) |
» |
Voltaite (Hydrated Potassium
Iron Sulfate) |
» |
Wherryite (Lead Copper Sulfate
Silicate Hydroxide) |
» |
Woodwardite (Hydrated Copper
Aluminum Sulfate Hydroxide |
» |
Zippeite (Hydrated Potassium
Uranyl Sulfate Hydroxide) |
The Phosphates Class
Including the Phosphates, the Uranyl
Phosphates, the Arsenates, the
Antimonates and the Vanadates.
The Phosphate Class is made up of
minerals with a basic chemical unit of
tetrahedral (AO4) groups with a negative
three (-3) charge. The A can be either
Phosphorus, Arsenic, Vanadium or
Antimony. The basic chemical unit can be
combined with metal ions on a one to one
ratio or usually in more complex
combinations with other ions such as
hydroxide groups (OH), uranyl groups
(UO2), a halogen or even water
molecules. The typical phosphate is
vitreous to dull, often strongly
colored, above average in density,
average in hardness (4-7) and law in
index of refraction unless ions such as
lead are present. All other properties
are variable. Many interesting and
beautiful mineral specimens come from
this class and although a large number
of minerals are known to belong to this
class, only some of the members of the
Apatite Group are considered common.
See also these subclasses: Arsenates,
Vanadates and the Antimonates
The Silicate Class
The Silicates are the largest, the most
interesting and the most complicated
class of minerals by far. Approximately
30% of all minerals are Silicates and
some geologists estimate that 90% of the
Earth's crust is made up of Silicates.
With oxygen and silicon the two most
abundant elements in the earth's crust
Silicates abundance is no real surprise.
The basic chemical unit of Silicates is
the (SiO4) tetrahedron shaped anionic
group with a negative four charge (-4).
The central silicon ion has a charge of
positive four while each oxygen has a
charge of negative two (-2) and thus
each silicon-oxygen bond is equal to one
half (1/2) the total bond energy of
oxygen. This condition leaves the
oxygens with the option of bonding to
another silicon ion and therefore
linking one (SiO4) tetrahedron to
another and another, etc..
The complicated structures that these
silicate tetrahedrons form is truly
amazing. They can form as single units,
double units, chains, sheets, rings and
framework structures. The different ways
that the silicate tetrahedrons combine
is what makes the Silicate Class the
largest, the most interesting and the
most complicated class of minerals.
The Silicates are divided into the
following subclasses, not by their
chemistries, but by their structures:
The Nesosilicate Subclass (single
tetrahedrons)
The simplest of all the silicate
subclasses, this subclass includes all
Silicates where the (SiO4) tetrahedrons
are unbonded to other tetrahedrons. In
this respect they are similar to other
mineral classes such as the sulfates and
phosphates. These other classes also
have tetrahedral basic ionic units (PO4
& SO4) and thus there are several groups
and minerals within them that are
similar to the members of the
nesoSilicates. NesoSilicates, which are
sometimes referred to as orthoSilicates,
have a structure that produces stronger
bonds and a closer packing of ions and
therefore a higher density, index of
refraction and hardness than chemically
similar Silicates in other subclasses.
Consequently, There are more gemstones
in the nesoSilicates than in any other
silicate subclass. Below are the more
common members of the nesoSilicates. See
the nesoSilicates' page for a more
complete list.
The Sorosilicate Subclass (double
tetrahedrons)
SoroSilicates have two silicate
tetrahedrons that are linked by one
oxygen ion and thus the basic chemical
unit is the anion group (Si2O7) with a
negative six charge (-6). This structure
forms an unusual hourglass-like shape
and it may be due to this oddball
structure that this subclass is the
smallest of the silicate subclasses. It
includes minerals that may also contain
normal silicate tetrahedrons as well as
the double tetrahedrons. The more
complex members of this group, such as
Epidote, contain chains of aluminum
oxide tetrahedrons being held together
by the individual silicate tetrahedrons
and double tetrahedrons. Most members of
this group are rare, but epidote is
widespread in many metamorphic
environments. Below are the more common
members of the soroSilicates. See the
soroSilicates' page for a more complete
list.
The Inosilicate Subclass (single and
double chains)
This subclass contains two distinct
groups: the single chain and double
chain Silicates. In the single chain
group the tetrahedrons share two oxygens
with two other tetrahedrons and form a
seemingly endless chain. The ratio of
silicon to oxygen is thus 1:3. The
tetrahedrons alternate to the left and
then to the right along the line formed
by the linked oxygens although more
complex chains seem to spiral. In cross
section the chain forms a trapezium and
this shape produces the angles between
the crystal faces and cleavage
directions.
In the double chain group, two single
chains lie side by side so that all the
right sided tetrahedrons of the left
chain are linked by an oxygen to the
left sided tetrahedrons of the right
chain. The extra shared oxygen for every
four silicons reduces the ratio of
silicons to oxygen to 4:11. The double
chain looks like a chain of six sided
rings that might remind someone of a
child's clover chain. The cross section
is similar in the double chains to that
of the single chains except the
trapezium is longer in the double
chains. This difference produces a
difference in angles. The cleavage of
the two groups results between chains
and does not break the chains thus
producing prismatic cleavage. In the
single chained Silicates the two
directions of cleavage are at nearly
right angles (close to 90 degrees)
forming nearly square cross sections. In
the double chain Silicates the cleavage
angle is close to 120 and 60 degrees
forming rhombic cross sections making a
convenient way to distinguish double
chain Silicates from single chain
Silicates. Below are the more common
members of the inoSilicates. See the
InoSilicates' page for a more complete
list.
The Cyclosilicate Subclass (rings)
These Silicates form chains such as in
the inoSilicates except that the chains
link back around on themselves to form
rings. The silicon to oxygen ratio is
generally the same as the inoSilicates,
(1:3). The rings can be made of the
minimum three tetrahedrons forming
triangular rings (such as in benitoite).
Four tetrahedrons can form a rough
square shape (such as in axinite). Six
tetrahedons form hexagonal shapes (such
as in beryl, cordierite and the
tourmalines). There are even eight
membered rings and more complicated ring
structures. The symmetry of the rings
usually translates directly to the
symmetry of these minerals; at least in
the less complex cycloSilicates.
Benitoite's ring is a triangle and the
symmetry is trigonal or three-fold.
Beryl's rings form hexagons and its
symmetry is hexagonal or six-fold. The
Tourmalines' six membered rings have
alternating tetrahedrons pointing up
then down producing a trigonal as
opposed to an hexagonal symmetry.
Axinite's almost total lack of symmetry
is due to the complex arrangement of its
square rings, triangle shaped borate
anions (BO3) and the position of OH
groups. Cordierite is pseudo-hexagonal
and is analogous to beryl's structure
except that aluminums substitute for the
silicons in two of the six tetrahedrons.
There are several gemstone minerals
represented in this group, a testament
to the general high hardness, luster and
durability. Below are the more common
members of the cycloSilicates. See the
CycloSilicates' page for a more complete
list.
The Phyllosilicate Subclass (sheets)
In this subclass, rings of tetrahedrons
are linked by shared oxygens to other
rings in a two dimensional plane that
produces a sheet-like structure. The
silicon to oxygen ratio is generally
1:2.5 (or 2:5) because only one oxygen
is exclusively bonded to the silicon and
the other three are half shared (1.5) to
other silicons. The symmetry of the
members of this group is controlled
chiefly by the symmetry of the rings but
is usually altered to a lower symmetry
by other ions and other layers. The
typical crystal habit of this subclass
is therefore flat, platy, book-like and
display good basal cleavage. Typically,
the sheets are then connected to each
other by layers of cations. These cation
layers are weakly bonded and often have
water molecules and other neutral atoms
or molecules trapped between the sheets.
This explains why this subclass produces
very soft minerals such as talc, which
is used in talcum powder. Some members
of this subclass have the sheets rolled
into tubes that produce fibers as in
asbestos serpentine.
Below are the more common members of the
phylloSilicates. See the PhylloSilicates'
page for a more complete list.
The Tectosilicate Subclass
(frameworks)
This subclass is often called the
"Framework Silicates" because its
structure is composed of interconnected
tetrahedrons going outward in all
directions forming an intricate
framework analogous to the framework of
a large building. In this subclass all
the oxygens are shared with other
tetrahedrons giving a silicon to oxygen
ratio of 1:2. In the near pure state of
only silicon and oxygen the mineral is
quartz (SiO2). But the tectoSilicates
are not that simple. It turns out that
the aluminum ion can easily substitute
for the silicon ion in the tetrahedrons
up to 50%. In other subclasses this
substitution occurs to a more limited
extent but in the tectoSilicates it is a
major basis of the varying structures.
While the tetrahedron is nearly the same
with an aluminum at its center, the
charge is now a negative five (-5)
instead of the normal negative four
(-4). Since the charge in a crystal must
be balanced, additional cations are
needed in the structure and this is the
main reason for the great variations
within this subclass. Below are the more
common members of the tectosilicate
subclass. See the tectoSilicates' page
for a more complete list.
The organics class of minerals cover
minerals that have an organic chemical
component in their formulas.
Mineral purists frown on there ever
being a mineral with an organic
chemistry. It breaks one of the four
rules that determine what is and what is
not a mineral. Or does it?
The four rules defining a mineral:
1. Minerals must have a repetitive
crystalline structure.!
2. Minerals must have a determinable and
precise formula.!
3. Minerals must be natural.!
4. Minerals must be inorganic.!
The last rule would exclude this class
of minerals. But rule number four is
really intended to exclude those
substances that are created in a
biological organism such as bones,
shells, pearls, ivory, etc. The minerals
in this class are created in a
geological setting, along with and
beside non-organic minerals. They just
happen to have organic chemicals in
their composition. The organic
chemicals, not the minerals, are
probably the result of biological
activities, but not necessarily. The key
here is that the minerals are the result
of geological activities and not
directly the product of organisms.
The Mineraloids Class:
The members of this unofficial class are
often mistaken for minerals and are
sometimes classified as minerals, but
lack the necessary crystalline structure
to be truly classified as such. Pearl,
jet and amber are in addition the
products of organic process that further
remove them from full mineral status.
These materials are found naturally,
some are treated as gemstones and are
included in most mineral references
(which is why we decided to include them
here!).
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